FREY SCIENTIFIC -- SODIUM HYDROXIDE -- 6810-00-234-8373
===================== Product Identification ===================== Product ID:SODIUM HYDROXIDE MSDS Date:12/23/1994 FSC:6810 NIIN:00-234-8373 === Responsible Party === Company Name:FREY SCIENTIFIC Address:905 HICKORY LANE City:MANSFIELD State:OH ZIP:44905 Country:US Info Phone Num:419-589-1900 Emergency Phone Num:800-424-9300(CHEMTREC) Preparer's Name:MICHEAL RASZEJA CAGE:6U218 === Contractor Identification === Company Name:FREY SCIENTIFIC Address:100 PARAGON PARKWAY Box:City:MANSFIELD State:OH ZIP:44905 Country:US Phone:419-589-1900 CAGE:6U218 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (CERCLA) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 90-100% Other REC Limits:NONE RECOMMENDED OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:DANGER!CORROSIVE!POISON!CAUSES SEVERE SKIN/EYE BURNS.MAY BE FATAL IF INGESTED.INGEST:POISON.MAY RESULT IN SEVERE INTESTINAL IRRIT W/BURNS TO MOUTH. SKIN/EYES:CONTACT W/SKIN/EYES MAY CAUSE SEVERE IRRIT OR BURNS. INHAL:DUST VERY IRRIT TO UPPER RESP TRACT. MAIN EFFECT. TISSUE DAMAGE. Effects of Overexposure:CORROSIVE, POISON. SEVERE SKIN/EYE BURNS. FATAL IF INGESTED, SEVERE INTESTINAL IRRIT W/BURNS TO MOUTH. VERY IRRITATING TO UPPER RESP TRACT. TISSUE DAMAGE. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMIT.IF CONSC GIVE LG AMTS OF WATER TO DRINK.FOLLOW W/WHITE OF EGGS BEATEN W/WATER.CALL DR IMMED.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.EYES:IMMED FLUSH W/LG AMTS OF WATER FOR 1 5MINS LIFTING EYELIDS.GET PROMPT MED ATTN.SKIN:FLOOD W/WATER THEN WASH W/VINEGAR.INHAL:REMOVE TO FRESH AIR.NOT BREATH GIVE ART RESP.DIFFICULT BREATH GIVE OXYGEN.GET MED ATTN. ===================== Fire Fighting Measures ===================== Flash Point:NON-COMBUSTIBLE Extinguishing Media:USE WATER ON FIRE INVOLVING THIS MATERIAL. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROT CLOTH.MUST INCLUDE COMPLETE EYE PROT.FLOOD W/WATER USING CARE NOT TO SPLATTER/SPALSH MATL.CONTACT W/WATER PRODUCES (SUPPLE Unusual Fire/Explosion Hazard:NOT COMBUST BUT SOLID FORM IN CONTACT W/MOISTURE/WATER MAY GENERATE SUFFICIENT HEAT TO IGN COMBUST MATLS.CONTACT W/SOME METALS CAN GENERATE HYDROGEN GAS.(SUPPL) ================== Accidental Release Measures ================== Spill Release Procedures:CAREFULLY & WEARING PROTECTIVE CLOTHING SWEEPUP & PLACE N SUITABLE CONTAINER.FLUSH SPILL AREA W/WATER RINSE W/DILUTE ACID PREFERABLY ACETIC & FINALLY W/WATER. Neutralizing Agent:SODIUM BISULFATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD.STORE IN COOL DRY PLACE;PROTECT AGAINST MOISTURE/WATER.SEPARATE FRM ACIDS/METALS/EXPLOSIVES/ORG PEROXIDES/EASILY IGN MATLS. Other Precautions:AVOID CONTACT W/SKIN/EYE/CLOTH.READ LABEL ON CNTNR BEF USING.PROD DELIQUESCENT;ABSORBS WATER/CO2 FRM AIR.NAOH & TRICHLOROETHYLENE ESPECIALLY HAZ--RX TO FORM SPONT FLAMM DICHLOROACETYLENE.FOR LAB USE O NLY.NOT FOR DRUG/FOOD/HOUSEHOLD USE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED IN NORMAL LABORATORY HANDLING. IF DUSTY CONDITIONS PREVAIL USE HIGH EFFICIENCY PARTICULATE RESPIRATOR. Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL) RECOMMENDED. Protective Gloves:RUBBER GLOVES. Eye Protection:CHEM SAF GOGG OR FACE SHIELD. Other Protective Equipment:GOGGLES,LAB COAT,APRON,VENTILATION HOOD,PROPER GLOVES,EYEWASH STATION.DO NOT WEAR CONTACT LENSES WHEN WORKING W/CHEMICAL Work Hygienic Practices:WASH CONTAMIN CLOTHING PROMPTLY.KEEP OUT OF REACH OF CHILDREN.WASH HANDS AFTER HANDLING. Supplemental Safety and Health FIREFIGHTING:INTENSE HEAT & HIGHLY IRRIT/CORR MIST. FIRE/EXPLO HAZ:HOT/MOLTEN MATL WILL RX VIOLENTLY W/WATER LIBERATING HEAT/CAUSING SPLASHING.SEVER EYE HAZ;SOLID/CONCEN SOLN DESTROYS TISSUE ON CONTAC T. DISPOSAL:TO SURFACE OF LIQ(AVOIDS VIOL SPLAT).NEUTRALIZE W/SODIUM BISULFATE.FLUSH TO SEWER W/COPIOUS AMTS OF WATER. ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:=1390.C, 2534.F Melt/Freeze Pt:=317.8C, 604.F Vapor Pres:1MM @739C Vapor Density:NONE LIST Spec Gravity:2.130 @25C pH:BASIC Evaporation Rate & Reference:NON-VOLATILE (N/A) Solubility in Water:19 G/100ML @20C Appearance and Odor:WHITE PELLETS OR FLAKES, NO ODOR. Percent Volatiles by Volume:NEGLIG ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER SOLNS RX VIOLENTLY W/ACIDS & W/MANY ORG CMPDS,MOST COMMON METALS(ZN,AL,SN,PB,ETC)LIBERATING FLAMM HYDROGEN. Stability Condition to Avoid:MOISTURE, ACIDS, ACID FUMES. Hazardous Decomposition Products:MAY FORM SODIUM MONOXIDE &/OR SODIUM PEROXIDE AT VERY HIGH TEMEPRATURES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJ TO FED/STATE/LOC LAWS.THESE GUIDELINES INTENDED FOR DISPOSAL OF CATALOG SIZE QUANT ONLY:AVOID BREATH DUST/MIST.WEAR FULL PROT CLOTH(GOGG,FACESHILED.SLOWLY DISS OLVE IN WATER.WHITLE MAKING SOLN ADD SLOWLY(SUPPL) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.